[Nb <sub>6</sub> Cl <sub>12</sub> (CH <sub>3</sub> OH) <sub>4</sub> (OCH <sub>3</sub> ) <sub>2</sub> ] ? DABCO ? 1.66 CH <sub>2</sub> Cl <sub>2</sub> : Cluster Units Wrapped in a Network of Hydrogen Bonds
نویسندگان
چکیده
An easy-to-do synthesis for the hexanuclear niobium cluster compound [Nb6Cl12(CH3OH)4(OCH3)2] ? DABCO 1.66 CH2Cl2 has been developed. one-pot reaction between precursor [Nb6Cl14(H2O)4] 4H2O and methanol with addition of leads to crystallization title in high yield within a few minutes. The single-crystal X-ray structure this determined. Very strong, nearly symmetric intercluster hydrogen bonds Nb6?MeO???H???OMe?Nb6 are present units. A bridging co-crystalline molecule is also involved three-dimensional hydrogen-bonding network.
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2021
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202100138